A comparison on the catalytic activity of Zn 1− xCo xFe 2O 4 ( x = 0, 0.2, 0.5, 0.8 and 1.0)-type ferrospinels prepared via. a low temperature route for the alkylation of aniline and phenol using methanol as the alkylating agent

Abstract

Depending on the variation of the Zn 2+/Co 2+ ratio in the Zn 1− x Co x Fe 2O 4 ( x=0, 0.2, 0.5, 0.8 and 1.0)-type ferrospinels, the systems showed different activity trends for aniline and phenol methylation using methanol as the alkylating agent. An increase in Zn 2+/Co 2+ ratio increased the rate of N-monomethylation of aniline, whereas, a decrease in the ratio favored the rate of ortho methylation of phenol. An attempt has been made to interpret the observed trends based on the variation of surface acid–base properties of the catalyst surface with changes in the spinel composition. The efficiency of adsorption of aniline, phenol or methanol depends not only on the catalyst surface acid–base properties but also on the polarity of the adsorbing molecules. A controlled interplay of surface acid–base properties and polarity of the respective reacting molecules determines the efficiency of a particular reaction. In the case of aniline methylation, surface basicity plays a dominating role, whereas for phenol methylation surface acidity plays a dominating role.