Abstract
The effect of the solgel and hydrothermal synthesis methods on the physicochemical properties and photocatalytic activity of nanohybrids consisting of nitrogen-doped TiO2 supported on varying ammounts (0 – 5 wt.%) of oxidized carbon nanotubes (NTiO2–oxCNT) are compared. Hydrothermal synthesis promotes the formation of cylindrical pores independent of oxCNT content while solgel synthesis results in closed pores which transition to an open cone shape upon incorporation of oxCNTs. The point of zero charge for the nanohybrids is in the acidic range. Hydrothermally synthesized nanohybrids demonstrated high photocatalytic decolorization (up to 99.8 %) of Reactive red 120 (RR 120) than their solgel-synthesized counterparts (up to 93.1 %). A 97.4 % decolorization and 84 % TOC removal was achieved by the nanohybrid NTiO2–oxCNT 5 wt.% oxCNT (5H) at 30 ppm RR 120. The LC−OCD-OND technique demonstrates that the nanohybrid (5H) is selective for the degradation of the biopolymers and low molecular weight neutrals in real industrial textile wastewater under 150 min under visible light.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.