A Comparison Between Kinetic Test Results and Natural Weathering: The Abandoned Kettara Mine Tailings Pond

Abstract

More than three million tons of sulfide tailings were discarded without any protection for more than 36 years at the since-abandoned Kettara mine. The impact of these tailings as well as the coarse wastes disorderly dumped on the surface site is highlighted by the elevated sulfate levels in the wells downstream of the wastes. Kinetic tests carried out on these sulfide tailings over 10 years ago, showed similar trends in metal dissolution despite large difference in test duration (21 and 53 weeks for the weathering and humidity cell tests, respectively). 40% of the sulfate release occurred in the first 3 weeks of the humidity test. However, in this study, the elevated sulfate levels in the groundwater was shown not be linked to the tailings, where the original sulfide material is still present under an oxidized layer of 10 cm–1.2 m. Thus, kinetic test results should not be extrapolated to field scale without accounting for site-specific factors, especially particle size and climate.