A comparative study on the pollution status of heavy metals in soils and sediment from farmlands in Askira Uba, Nigeria

Abstract

Heavy metals may enter the food chain from soil through mineralization by crops or environmental contamination, as in application of agricultural inputs such as pesticides and fertilizers or in the treatment of soils with sewage sludge cupper content of normal plant tissue. Atomic Absorption Spectroscopic (AAS) method is one of the most commonly used instrument in metal analysis due to its reproducibility of results, short analysis time, lower level of detection. Soil and sediments samples were collected at three distinct stations each, designated as A1, B1, C1 and A2, B2, C2 respectively from Askir/Uba local government area of Borno State, Nigeria. The concentrations of six heavy metals of environmental concern which includes Cd, Cu, Cr, Pb, Ni and Zn were determined by Atomic Absorption Spectrophotometer; Buck scientific model 210GP. The mean concentration of Cd in soil and sediment were (10.7±2.32 mg/kg and 9.62±2.32 mg/kg) and are of toxicological concern. The decrease in concentrations of the metals across sampling locations followed this order Cd > Cu > Cr > Pb > Ni > Zn. The geoaccumulation index of the sediment by each metals are in the following increasing order: B2 < A2 < C2 for Cd and Pb, B2 < C2 < A2 for Cr, A2 < B2 < C2 for Cu, A2 < B2 < C2 for Zn respectively. In general, the order of metal contamination were Zn < Ni < Cu < Pb < Cr < Cd. The results of the findings revealed that the soil and sediment were contaminated with Cadmium, the high level of Cd in the soil were above the recommended values. However, Independent-samples t-test (statically significant at p<0.05) was used to compared the average metal composition in soil and sediment which showed that there was no significant difference on the composition in soil and sediment for all the metals p-value = 0.8939 The aim of the study was to compare the mean level of the soil and sediment with WHO permissible limit, hence evaluate their pollution status by the application of geoaccumulation index.