A comparative study on the hydriding kinetics of Zr-based AB 2 hydrogen storage alloys

Abstract

Two kinetic models (Jander model and Chou model) are used to investigate the hydrogen absorption kinetic mechanism of Zr-based AB 2 type Laves phase alloys (Ti 0.1Zr 0.9Mn 0.9V 0.1Fe 0.5Co 0.5, Ti 0.1Zr 0.9(Mn 0.9V 0.1) 1.1Fe 0.5Ni 0.5 and Ti 0.1Zr 0.9Mn 0.9V 0.1Fe 0.55Ni 0.55). The analysis shows that the rate-controlling step is the diffusion process at high temperatures in the range from 673 K to 923 K with a low hydrogen concentration (solid solution phase). Both models can well describe the experimental data but Chou model is preferred. Chou model is simpler and easier to use for analyzing the experimental results. The activation energies calculated using Chou model with the least square method are 29.3 kJ/mol H 2 for Ti 0.1Zr 0.9Mn 0.9V 0.1Fe 0.5Co 0.5, 43.8 kJ/mol H 2 for Ti 0.1Zr 0.9(Mn 0.9V 0.1) 1.1Fe 0.5Ni 0.5 and 48.5 kJ/mol H 2 for Ti 0.1Zr 0.9Mn 0.9V 0.1Fe 0.55Ni 0.55, which are close to the values reported in the literature (28.3 kJ/mol H 2 for Ti 0.1Zr 0.9Mn 0.9V 0.1Fe 0.5Co 0.5 and 40.3 ± 1.5 kJ/mol H 2 for both Ti 0.1Zr 0.9(Mn 0.9V 0.1) 1.1Fe 0.5Ni 0.5 and Ti 0.1Zr 0.9Mn 0.9V 0.1Fe 0.55Ni 0.55).