A comparative study on NH3/H2 and NH3/CH3OH combustion and emission in an optical SI engine

Abstract

Ammonia is an attractive carbon-free fuel but suffers from poor combustion characteristics and heavy emissions. Green hydrogen and methanol are recognized as the most promising combustion promoters for enhancing ammonia reactivity in pursuit of a carbon–neutral solution. Nonetheless, a comparative study on ammonia combustion and emissions, incorporating hydrogen and methanol enrichment, is currently absent under actual engine conditions. In this work, the combustion performance, visualized flame characteristics, and pollution emissions of ammonia were investigated in an optical engine, allowing for low-level hydrogen and methanol enrichment, specifically at energy ratios of 5%, 10%, and 15%. We have identified the crucial role of hydrogen and methanol enrichment in enhancing various aspects of ammonia engine performance, including thermal efficiency, combustion stability, flame initiation and propagation, and nitrogen-based emissions. Specifically, hydrogen enrichment demonstrates a more pronounced effect on reducing cyclic variations, whereas methanol enrichment exhibits a greater influence on increasing thermal efficiency, manifesting improved controllability in combustion phasing. Combustion visualizations show the contribution of hydrogen enrichment to the formation process of the initial flame kernel, which is reflected as a lower cyclic variation from a macroscopic perspective, and meanwhile, methanol enrichment features a stronger acceleration effect during the turbulent flame propagation process. Furthermore, the quantification of flame response to turbulence is solved and observed much higher effects for NH3/CH3OH blends than for NH3/H2 blends, indicating a distinctly different mechanism of facilitation by methanol enrichment. Regarding nitrogen-based emissions, both hydrogen and methanol enrichment lead to a substantial reduction in NH3 slip and N2O emissions, consistent with observed variations in combustion stability. However, methanol enrichment induces noticeable decreases in NOx emissions, while hydrogen enrichment exhibits an opposing trend. The present study demonstrates the beneficial impacts of hydrogen and methanol enrichment on improving ammonia combustion and emissions, with the underlying reason correlated to flame dynamics and thermochemical interactions.