Abstract

In calcined and rehydrated VSis zeolite prepared following a method described earlier, three kinds of tetrahedral VV species can be clearly identified by photoluminescence spectroscopy even at low V content, in contrast to 51V NMR and diffuse reflectance UV-Visible spectroscopies which do not allow them to be distinguished. A comparative study by photoluminescence and 51V NMR spectroscopies leads to the suggestion that there is a correlation between the vibrational energy of the V=O bond and the corresponding chemical shift of the 51V NMR signal.

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