Abstract
The transport and separation of mixtures between benzene and p-xylene in pellets prepared by pressing of ZSM-5 powder and a dense supported (crystalline) Silicalite-1 membrane were compared to isolated ZSM-5 crystallites. The kinetics of the transport in the pressed pellet and the grown membrane determined in a Wicke–Kallenbach cell (313–403 K; partial pressure range 200–2300 Pa) differed significantly from those measured for isolated ZSM-5 particles with the pressure modulation frequency response technique (343–403 K; partial pressure 30 Pa). In a pressed pellet, the transport was of Knudsen type leading to high fluxes of 10 −4 mol/m 2 s and identical permeances for benzene and p-xylene. The diffusion coefficient in a pressed pellet exceeded that in particles, in which the transport was controlled by intracrystalline diffusion and the pore entrance step, by 8 orders of magnitude. The flux across a grown Silicalite-1 membrane was two orders of magnitude lower and the permeability of p-xylene was 2.6–5 times higher than that of benzene. The change in diffusivity in the membrane compared to the particles results from the higher surface coverage of p-xylene.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
