A comparative study of adsorption of perfluorooctane sulfonate (PFOS) onto granular activated carbon, ion-exchange polymers and non-ion-exchange polymers

Abstract

Perfluorooctane sulfonate (PFOS) is the latest chemical categorized as persistent organic pollutants (POPs). PFOS appears in the environmental water and tap water in ng L −1 level. The process of adsorption has been identified as an effective technique to eliminate PFOS in water. Three non-ion-exchange polymers (DowV493, DowL493 and AmbXAD4), two ion-exchange polymers (DowMarathonA and AmbIRA400) and one granular activated carbon (GAC) (Filtersorb400) were tested with regard to their sorption kinetics and isotherms at low PFOS concentrations (100–1000 ng L −1 equilibrium concentrations). The sorption capacities at 1 μg L −1 equilibrium concentration decreased in the following order: Ion-exchange polymers > non-ion-exchange polymers > GAC, but at further low equilibrium concentration (100 ng L −1) non-ion-exchange polymers showed higher adsorption capacity than other adsorbents. In the case of sorption kinetics, GAC and ion-exchange polymers reached the equilibrium concentration within 4 h and AmbXAD4 within 10 h. DowV493 and DowL493 took more than 80 h to reach equilibrium concentration. AmbIRA400 was identified as the best filter material to eliminate PFOS at equilibrium concentration >1000 ng L −1. Considering both adsorption isotherms and adsorption kinetics, AmbXAD4 and DowMarathonA were recommended to eliminate PFOS at ng L −1 equilibrium concentration.