A comparative study for the removal of reactive red 49 (RR49) and reactive yellow 15 (RY15) using a novel electrode by electrocoagulation technique

Abstract

The present work deals with the investigation of the efficiency of the electrocoagulation (EC) technique in the removal of two different reactive dyes as a simple, durable, and cost-effective technique for wastewater treatment. The difference in structure between Reactive Red 49 (RR49) and Reactive Yellow 15 (RY15) is explored during the treatment process through the use of a novel design of electrodes. The optimum conditions obtained were 80 and 60 mg/L of initial dye concentrations, pH of 5.9 and 4 for RR49 and RY15, respectively, 0.5 g of NaCl electrolyte, and 900 and 500 rpm of stirring rate for RR49 and RY17 dyes respectively, which led to the highest percent removal (98.5%) for both dyes. The suitable temperatures were 20 and 30 °C for RR49 and RY15, respectively. The thermodynamic parameters were designated, and it was a spontaneous process for both dyes. The removal process was designated to pseudo- second-order for the RR49 dye and pseudo- first-order for the RY15 dye and fitted to the Langmuir model. Analysis of Variance (ANOVA) was presented to assess the variation of the outcomes attained from each factor.