Abstract
Environmentally friendly energy storage devices have been fabricated by using functional materials obtained from completely renewable resources. Gelatin, chitosan, casein, guar gum and carboxymethyl cellulose have been investigated as sustainable and low-cost binders within the electrode active material of water-processable symmetric carbon-based supercapacitors. Such binders are selected from natural-derived materials and industrial by-products to obtain economic and environmental benefits. The electrochemical properties of the devices based on the different binders are compared by using cyclic voltammetry, galvanostatic charge/discharge curves and impedance spectroscopy. The fabricated supercapacitors exhibit series resistance lower than a few ohms and values of the specific capacitance ranged between 30 F/g and 80 F/g. The most performant device can deliver ca. 3.6 Wh/kg of energy at a high power density of 3925 W/kg. Gelatin, casein and carboxymethyl cellulose-based devices have shown device stability up to 1000 cycles. Detailed analysis on the charge storage mechanisms (e.g., involving faradaic and non-faradaic processes) at the electrode/electrolyte interface reveals a pseudocapacitance behavior within the supercapacitors. A clear correlation between the electrochemical performances (e.g., cycle stability, capacitance retention, series resistance value, coulombic efficiency) ageing phenomena and charge storage mechanisms within the porous carbon-based electrode have been discussed.
Highlights
Published: 24 December 2021The rapid development and diffusion of electronic products in everyday life within a broad application range imply an ever-increasing energy consumption
Among electrochemical energy storage devices, supercapacitors, known as electrochemical capacitors, are under intensive academic and industrial investigations in recent years since they have distinct advantages such as higher power density due to the fast charging/discharging rate and long-life stability when compared to batteries and fuel cells [2]
Supercapacitors (SCs) are composed of a medium sandwiched between two high-surface-area electrodes, a simple and highly versatile structure that match the requirements for consumer electronics addressed to be smaller, lighter, thinner, and flexible in the near future
Summary
The rapid development and diffusion of electronic products in everyday life within a broad application range imply an ever-increasing energy consumption. In this context, the opportunity to store energy to deliver power on demand has become a crucial aspect for the more efficient use of energy [1]. Among electrochemical energy storage devices, supercapacitors, known as electrochemical capacitors, are under intensive academic and industrial investigations in recent years since they have distinct advantages such as higher power density due to the fast charging/discharging rate and long-life stability when compared to batteries and fuel cells [2]. The growing demand for consumer electronics led to large amounts of electrical and electronic waste equipment that pose environmental concerns [3].
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