Abstract

Solar thermal absorber coatings play a key role in the thermal efficiency of receivers for applications in the field of Concentrated Solar Power (CSP). The development of stable spectral selective coatings with a high solar absorptance αsol and a low thermal emittance εth is often desired to reduce thermal losses. However, quantitative indicators describing selectivity and the trade-off between solar absorptance and thermal emittance is seldom discussed in the literature.In this review, relevant opto-thermal figures of merit are analyzed for the comparison of reference solar thermal absorber coatings, including real and ideal coatings, both black and spectral selective. The comparison is made for a temperature ranging from 25 to 1000 °C and for a concentration factor ranging from 20 to 1000, based on spectral data measured at room temperature from 0.25 to 20 μm.New figures of merit are introduced, i.e. a normalized selectivity ratio Si*, a trade-off factor Ztrade-off, a normalized solar reflectance index SRI* and a peak efficiency temperature Tpeak,opt. These metrics are derived from existing figures of merit and adapted for CSP.The set of figures of merit analyzed in this review offer a complementary perspective for the detailed characterization of any coating opto-thermal performance. For solar thermal absorber coatings, thermal efficiency ηthermal and peak efficiency temperature Tpeak,opt are respectively deemed more insightful than opto-thermal efficiency ηopt-th and maximum steady-state temperature TSST,max, when comparing the relative opto-thermal performance of two coating formulations.

Highlights

  • Concentrated solar radiation can be harnessed and converted into electrical power by different technologies

  • Direct conversion can be achieved by Concentrated Photovoltaics (CPV) [1,2] or Solar Thermo­ electric Generators (STEG) [3,4,5]

  • Conventional thermo­ dynamic power cycles can be driven by the heat generated with Concentrated Solar Thermal (CST) systems, such as Parabolic Trough Collectors (PTC) [6,7,8] Linear Fresnel Collectors [9,10], Central Receiver Systems CRS [11,12,13,14] or dish concentrators [15,16]

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Summary

Introduction

Concentrated solar radiation can be harnessed and converted into electrical power by different technologies. Conventional thermo­ dynamic power cycles can be driven by the heat generated with Concentrated Solar Thermal (CST) systems, such as Parabolic Trough Collectors (PTC) [6,7,8] Linear Fresnel Collectors [9,10], Central Receiver Systems CRS [11,12,13,14] or dish concentrators [15,16]. Hybrid solar concentrators exist, for example taking advantage of spectral beam-splitting devices, to focus solar radiation on multiple receiver types and increase further the conversion efficiency [17,18,19]. These concentrating systems consist of optical concentrators tracking the sun and focusing Direct Normal Irradiance (DNI) onto a receiver. The integration of molten salt thermal storage tanks allows a cost-efficient and dispatchable power generation [23]

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