Abstract

Abstract A new cobalt-based coordination polymer (CP), [Co(Htatb)(1,4-bib)]·DMF (1), has been hydrothermally synthesized from CoCl2 ·6H2O, 4,4′,4′′-s-triazine-2,4,6-tribenzoic acid (H3tatb), and 1,4-bis(1-imidazoly)benzene (1,4-bib). The product has been characterized by IR spectroscopy, elemental and thermogravimetric analysis, and single-crystal X-ray diffraction. In compound 1, the Htatb ligand links three CoII ions resulting in a double-strand chain structure, further bridged through the 1,4-bib ligands to generate a 2D structure with channels. The fluorescence and cyclovoltammetry characteristics of compound 1 have also been investigated.

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