Abstract
Abstract A chiral helical MOF [Mn2(sac)2(H2O)2]·3.3H2O (H2sac = d -saccharic acid) (1) has been synthesized and characterized. MOF 1 crystallizes in orthorhombic system with space group P212121, and the structure contains right-handed 21 helical chains in three directions with hydrophilic channels. From the topological point of view, the framework of MOF 1 can be abstracted as an unusual binodal 3-connected network with utg topology. The electrochemical property has been studied, undergoing two one-electron redox processes.
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