Abstract
A novel 3d–4f heterometallic coordination complex [Ce(H2O)6 (CuL)2]·NO2·7H2O (1) (H3L = glycylglycine, N-[1-(2-hydroxy, phenyl)-propylidene]) was synthesized and characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. An octameric water cluster consisting of a planar tetrameric water ring and four dangling water molecules were observed in 1. Variable-temperature magnetic data shows antiferromagnetic behavior for 1.
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