A case study of optical and chemical ground apportionment for urban aerosols in Thessaloniki

Abstract

Urban aerosol characterization gathering ground-based in situ and sunphotometer measurements have been performed for the city of Thessaloniki for two specific days: the 12th and 13th of June 1997. A representative aerosol model for Thessaloniki aerosols was tentatively constructed for each day. Four components have been selected from our chemical measurements: black carbon (BC), particulate organic matter (POM), inorganic fine water soluble particles (WS) and a residue coarse component which mainly contains coarse dust and sea-salt particles (CC). Size distribution and complex refractive index for (WS) and (CC) components were determined from published data. (CC) has been shown to have a small optical effect compared to the submicron components. Size distribution for carbonaceous particles was obtained from sensitivity tests on particulate number and visible Angström exponent. The impact of relative humidity on extinction and scattering coefficients has been calculated on 13 June with Mie theory and Hänel relationships. Parameters needed for this calculation were well known for WS particles only. For POM particles we have used the experimental curve of hygroscopic factors obtained by Hobbs et al. (1997) for urban aerosols sampled on the East coast of United States to determine the hydrophilic dependency of POM particles. Relative humidity has been shown to be an important parameter even for values lower than 50%. Optical apportionment calculation has been realized pointing out that more than 45% of the total extinction coefficient is due to (POM) particles and about 20 and 30% to (WS) and (BC), respectively.