A carbon nanotube sponge as an adsorbent for vapor preconcentration of aromatic volatile organic compounds

Abstract

A carbon nanotube (CNT) sponge was synthesized and examined as an adsorptive material for a thermally desorbed preconcentrator for volatile organic compounds (VOCs). The porous sponge-like material, retaining the intrinsic properties of individual multiwalled (MW) CNTs, was fabricated using spray pyrolysis chemical vapor deposition (CVD). The square pillar form of the CNT sponge was enclosed in a 1/4″ glass tube with fittings for flow-through sampling. Flow of a direct current through the CNT sponge allowed rapid thermal heating to a surface temperature of 264.7 ℃ at a rate of 481.5 ℃/s and a narrow desorption bandwidth of 0.74 s. The preconcentration concept was validated using gas chromatographic analysis of an aromatic VOC mixture, including benzene, toluene, ethylbenzene, and o-xylene (BTEX) vapors at concentrations of 100 parts per billion (ppb). With an adsorption volume of only 100 mL, the enrichment factor of each analyte was 300 (B), 240 (T), 210 (E), and 200 (X), enabling sensitive measurements with limits of detection at the parts per trillion level. Sequential desorption experiments confirmed that a single desorption process evaporates all the analytes inside the preconcentrator with >96% efficiency. There was no humidity effect and no sign of performance degradation after continuous operation for 45 repeated cycles. These results demonstrate that CNT sponges are a suitable material for the enrichment and sensitive determination of VOCs at trace levels. Thus, CNT sponge preconcentrators are advantageous in a variety of applications that permit fast and accurate real-time measurements, including ambient air and workplace air monitoring.