Abstract

A luminescent coordination cage formulated as {Mg24(TC4A)6(BTC)8(H2O)6} (SWU-2, H4TC4A = p-tert-butylthiacalix[4]arene, H3BTC = 1,3,5-benzenetricarboxylic acid) was successfully synthesized by the assembly of Mg4-TC4A units with BTC ligands.

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