A Brief Review of MoO3 and MoO3-Based Materials and Recent Technological Applications in Gas Sensors, Lithium-Ion Batteries, Adsorption, and Photocatalysis.

Abstract

Molybdenum trioxide is an abundant natural, low-cost, and environmentally friendly material that has gained considerable attention from many researchers in a variety of high-impact applications. It is an attractive inorganic oxide that has been widely studied because of its layered structure, which results in intercalation ability through tetrahedral/octahedral holes and extension channels and leads to superior charge transfer. Shape-related properties such as high specific capacities, the presence of exposed active sites on the oxygen-rich structure, and its natural tendency to oxygen vacancy that leads to a high ionic conductivity are also attractive to technological applications. Due to its chemistry with multiple valence states, high thermal and chemical stability, high reduction potential, and electrochemical activity, many studies have focused on the development of molybdenum oxide-based systems in the last few years. Thus, this article aims to briefly review the latest advances in technological applications of MoO3 and MoO3-based materials in gas sensors, lithium-ion batteries, and water pollution treatment using adsorption and photocatalysis techniques, presenting the most relevant and new information on heterostructures, metal doping, and non-stoichiometric MoO3-x.