Abstract
Synthesis of a bulky anilidophosphine ligand (short PNTerph) and its lanthanum complexes 1 and 3 is reported. When exposed to KPHMes, both complexes form the first example of a bis-phosphanido-phosphinidene complex 2. This complex undergoes Phospha-Wittig type reactions and its reactivity towards strong bases is further investigated.
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