Abstract
• Brass-mesh structured reactor with large surface area was used for RB5 degradation. • The washcoating technique provided a layer with high content of immobilized catalyst. • The use of solar radiation indicated a photocatalytic efficiency of 67.5%. • The monolith showed good stability after 5 cycles of photocatalytic reaction. • The studied photoreactor is a promising alternative for textile dye degradation. A photocatalytic structured reactor of calcined brass-mesh monolith immobilized with TiO 2 was built for textile dye photodegradation. The photocatalytic efficiency of these materials was investigated at the reactive black 5 (RB5) degradation at a recycle reactor. The effects of feed flow (1, 2, and 3 L h −1 ), pH medium (4, 7, and 9), and the radiation source (solar and artificial) were studied. The results of the tests performed with artificial radiation (UV-A and UV-B) showed that the flow modification did not lead to a significant difference in the degradation of the dye chromophore group, thus proving the structured system characteristics when operating at high flow values. Regarding the radiation type, the use of solar radiation indicated a photocatalytic efficiency of 67.5%. The monolithic systems also showed good stability after 5 consecutive cycles of photocatalytic reaction, maintaining a degradation higher than 80%. It was observed that the toxicity tests of seeds and bacteria illustrated that the products obtained after the photodegradation were not toxic, guaranteeing the quality of water. Based on the results obtained in this work, the brass-mesh monolith consists of an efficient system for RB5 degradation, rising as a promising alternative to textile effluent treatment. Graphical Abstract .
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Chemical Engineering and Processing - Process Intensification
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.