Abstract
Wolkenstein's bond polarizability approach to Raman intensities is applied to the terminal carbonyls stretching vibrations of some metal carbonyl species. General intensity formulae are given and the cases of M(CO)6(M = Cr, Mo, and W); RM (CO)3[RM =(π-C5H5)Mn or (arene)Cr, arene = simple or substituted benzene rings]; RM(CO)5(RM = BrMn and Ph3SnRe) are discussed in detail.
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