Abstract

We have developed a bond-based peridynamics model to study the fracture of polymer networks under finite deformation. Our approach is based on the Kuhn–Grün model of randomly jointed polymers with extensible chains, which allows the rupture of polymers through the chain scission mechanism. We introduced a novel mesoscale potential function that intrinsically incorporates an Arruda–Boyce type model into a nonlocal continuum framework with the purpose of modeling the mechanical response of general polymeric materials and the fracture of polymers. We have demonstrated through a series of numerical examples, both two-dimensional and three-dimensional, that the proposed model is robust and efficient in modeling crack growth in polymeric materials. The model is carefully validated with experimental data and numerical results obtained on the basis of existing continuum mechanics polymer models. We have shown that the proposed peridynamic model is accurate and stable in various configurations and loading modes, such as mode I and shear crack opening. In comparison to existing continuum polymer models and fracture modeling methods, our present technique has the advantages of being theoretically simple, rigorous, and computationally fast. The numerical results show that the nonlocal polymer model can easily capture the fracture process in polymeric materials without complex ad hoc modeling parameters under finite deformation, and it has the potential to become a convenient simulation tool for modeling the polymer failure process in the design and optimization of polymeric materials.

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