A blend of stretching and bending in nematic polymer networks.

Abstract

Nematic polymer networks are (heat and light) activable materials, which combine the features of rubber and nematic liquid crystals. When only the stretching energy of a thin sheet of nematic polymer network is minimized, the intrinsic (Gaussian) curvature of the shape it takes upon (thermal or optical) actuation is determined. This, unfortunately, produces a multitude of possible shapes, for which we need a selection criterion, which may only be provided by a correcting bending energy depending on the extrinsic curvatures of the deformed shape. The literature has so far offered approximate corrections depending on the mean curvature. In this paper, we derive the appropriate bending energy for a sheet of nematic polymer network from the celebrated neo-classical energy of nematic elastomers in three space dimensions. This task is performed via a dimension reduction based on a modified Kirchhoff-Love hypothesis, which withstands the criticism of more sophisticated analytical tools. The result is a surface elastic free-energy density where stretching and bending are blended together; they may or may not be length-separated, and should be minimized together. The extrinsic curvatures of the deformed shape not only feature in the bending energy through the mean curvature, but also through the relative orientation of the nematic director in the frame of the directions of principal curvatures.