Abstract

Solar thermal energy regulation is important for sustainable development, comfortable housing, and living. Black compounds are usually considered as an absorber of solar heat. This work reports a series of black near-infrared reflective pigments, Ca2-yMgyMn(1)1-xMn(2)xO4 (x = 0–1, y = 0–0.5), which show strong near-infrared (NIR) reflectivity. Comprehensive analyses were carried out to characterize the obtained pigments including X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and UV–Vis–NIR spectrophotometry. Through the substitution of MnO2 with Mn2O3, NIR solar reflectance of the black pigment can be enhanced by 13%, which might be mainly attributed to differences in particle size and lattice parameters. Meanwhile, through Mg doping, the obtained pigment Ca1.8Mg0.2MnO4 shows excellent color performances (L* = 43, a* = 0.36, b* = −0.37) and NIR solar reflectance (R*, ∼60%). EnergyPlus simulation results show that for a warm city (Haikou), using the Ca1.8Mg0.2MnO4 coating (L* = 25, R* = 51%) can reduce annual cooling energy consumption by 21%.

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