Abstract
Herein, we report the synthesis of a flexible bis-cyclopentadienyl ligand L (the doubly deprotonated form of H2L (1,3-bis(2,4-di-tert-butylcyclopentadienyldimethylsilyl)benzene)), demonstrating its ability to stabilize a series of di-iron hydrido complexes. Notably, this ligand facilitates the isolation of an unprecedented anionic cyclopentadienyl ligand-supported di-iron trihydride complex, LFe2(μ-H)3Li(THF) (2), functioning as a synthon for the [Fe2(μ-H)3]- core and providing access to heterobimetallic complexes 4-6 with coinage metals.
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