Abstract
A binary system of two ionic liquids, 1-ethyl-3-methylimidazolium and trioctylmethylammonium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2 ] and [OMA][NTf2 ], respectively), with varying molar fractions, is introduced. It allows the dynamic viscosity to remain constant over a range of almost 60 K; this means that any activated process can be studied independent of the temperature dependence of viscosity itself. This principle is proven upon reinvestigation of electron self-exchange kinetics of tetrathiafulvalene by continuous-wave ESR line-broadening experiments. From these results, it is also confirmed that this process is totally diffusion controlled.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Chemphyschem : a European journal of chemical physics and physical chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
