Abstract

The reaction between (dppe) 2W(N 2) 2 and CNC 6H 4NC produces (dppe) 2CNC 6H 4NCWCNC 6H 4NCWCNC 6H 4NC(dppe) 2, a dimer containing electron-rich metal centers, a protective sheath of organic ligands, and terminal free isocyanide groups.

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