A Bifunctional Hybrid Electrocatalyst for Oxygen Reduction and Evolution: Cobalt Oxide Nanoparticles Strongly Coupled to B,N-Decorated Graphene.

Abstract

The electrocatalyzed oxygen reduction and evolution reactions (ORR and OER, respectively) are the core components of many energy conversion systems, including water splitting, fuel cells, and metal-air batteries. Rational design of highly efficient non-noble materials as bifunctional ORR/OER electrocatalysts is of great importance for large-scale practical applications. A new strongly coupled hybrid material is presented, which comprises CoOx nanoparticles rich in oxygen vacancies grown on B,N-decorated graphene (CoOx NPs/BNG) and operates as an efficient bifunctional OER/ORR electrocatalyst. Advanced spectroscopic techniques were used to confirm formation of abundant oxygen vacancies and strong Co-N-C bridging bonds within the CoOx NPs/BNG hybrid. Surprisingly, the CoOx NPs/BNG hybrid electrocatalyst is highly efficient for the OER with a low overpotential and Tafel slope, and is active in the ORR with a positive half-wave potential and high limiting current density in alkaline medium.