Abstract
A dinuclear class-I mixed valence cobalt(III)/cobalt(II) complex, [(N3)CoIIIL(µ-C6H5COO)CoII(N3)]·CH3OH [where H2L = (1,3-propanediyl)bis(iminomethylene)bis(6-methoxyphenol)] has been prepared and characterized by elemental and spectral analysis. The structure of the complex has been confirmed by single crystal X-ray diffraction analysis. The cobalt(III) center is placed in the inner N2O2 compartment, whereas cobalt(II) center is present in the outer O4 compartment of the ligand. The complex may act as active functional model for the oxidation of 2-aminophenol to 2-aminophenoxazine-3-one with kcat = 153.90 h−1.
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