Abstract

We report on superconducting and magnetic characteristics in four-layered high-Tc superconductors Ba2Ca3Cu4O8(FyO1−y)2 with apical fluorine through 63Cu-NMR measurements. The temperature dependence of the Knight shift shows that the substitution of oxygen for fluorine at the apical site increases carrier density (Nh) and Tc from 55 up to 102 K. The 63Cu-NMR spectra suggest that antiferromagnetic (AFM) order takes place in underdoped CuO2 layers; especially, the AFM order coexists with superconductivity in a single CuO2 plane at y=1.0.

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