Abstract
This paper describes a novel heteropolynuclear coordination polymer [Cd4Co2(m-BDC)6(HIm)4]n (1) (m-H2BDC=1,3-benzenedicarboxylic acid, Him=imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (44·62)(48·66·8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5–300K.
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