Abstract
A new cadmium(II) coordination polymer [Cd2(L)2(bpy)]n·nCH3OH (1) (H2L=2-(3-oxo-3-phenylpropionyl)-6-pyridinecarboxylic acid N-oxide, bpy=4,4′-bipyridine), has been synthesized from the reaction of H2L, 4,4′-bipyridine with CdSO4·8/3H2O. Compound 1 is an exceptional non-interpenetrating three-dimensional framework and contains double helical chains and rare cross bpy configuration. Interestingly, these helical chains can span two different directions on other alternate layers. Compound 1 shows intense photoluminescence at room temperature.
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