Abstract
A new oxo-centered, carboxylate bridged trinuclear mixed-valence iron coordination polymer has been obtained under hydrothermal conditions, [(FeIII)2FeII(μ3-O)(BNA)6]n (1). Single crystal X-ray diffraction analysis of the black crystal reveals that three iron atoms occupy the vertices of a non-equilateral triangle with the Fe┄Fe distance in the range of 3.245 Å–3.343 Å and are bonded by the μ3-oxo-centered and BNA− ligands. The crystal belongs to the monoclinic crystal system with a = 11.2904(6) Å, b = 18.4960(11) Å, c = 21.4349(12) Å, β = 91.029(1), space group P21/c, GOF = 1.028, final R1 = 0.0156, wR2 [I > 2σ(I)] = 0.0405.
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