Abstract
The reaction of 1,3,5-tri(1,2,4-triazol-1-ylmethyl)-2,4,6-trimethylbenzene (ttmb) with CuCl 2 yields a coordination polymer [Cu 3 (ttmb) 2 (H 2 O) 6 Cl 6 ] n ·3 n H 2 O ( 1 ). The flexible ligand ttmb shows the cis,cis,cis -conformation and a tri-monodentate coordination mode in 1 . Each ttmb links three Cu(II) atoms to form an undulated (3,4)-connected two-dimensional network. Each undulated two-dimensional network polycatenates other two identical networks, thus giving a rare (2D → 3D) parallel polycatenation network in 1 . The thermal stability of compound 1 was studied.
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