Abstract
A novel 2-D coordination polymer constructed by μ 2-acetate-O,O ′, μ 2-hydroxo, μ 2-aqua and 4,4 ′-bipyridine (bipy) ligands has been synthesized and structurally characterized. Linear 1-D chain built by bridged μ 2-acetate-O,O ′, μ 2-hydroxo and μ 2-aqua units is composed of Cu 2O 2 motifs and syn-anti bridged acetate ligands. The copper atom with a five-coordination has a distorted square-pyramidal geometry completed by two nitrogen atoms from 4,4 ′-bipyridine and three oxygen atoms from acetate, hydroxo and water ligands. The strong stacking effect is observed between 4,4 ′-bipyridine ligands.
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