Abstract
A novel cobalt–thiacalix[4]arene compound, [Co4Cl2(TC4A)(ptz)2]∙H2O (where H4TC4A=p-tert-butylthiacalix[4]arene; ptz=5-(4-pyridyl)tetrazolate) was obtained by solvothermal method, in which ptz was in situ-generated by click reaction of 4-cyanopyridine and sodium azide. This compound is featured with some wavelike layer motifs constructed by bridging the shuttlecock-like Co4-TC4A secondary building units (SBUs) with in situ-generated ptz ligands. Magnetic measurement reveals that the cobalt (II) centers exhibit antiferromagnetic interactions.
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