Abstract
13C ENDOR spectra of Cu(et 2dtc) 2 substituted into a single crystals of Zn(et 2dtc) 2 are reported. The symmetry of the incorporated guest molecule appears to be considerably influenced by the Zn(et 2dtc) 2 host lattice. The unexpectedly large isotropic 13C hfs coupling can be understood assuming a “transannular overlap” mechanism.
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