Abstract

Photochemically-initiated oxidative fission of the MoMo bond in [C 5H 5Mo(CO) 3] 2 by the ferricenium salt [(C 5H 5) 2Fe]BF 4 in the presence of four equivalents of L affords a good yield of [C 5H 5Mo(CO) 2L 2]BF 4 (L = group 15 donor ligands). 95Mo NMR data are reported and discussed together with the NMR and IR data of new complexes. Decomposition of the title cations in polar solvents affords low yields of the corresponding [C 5H 5MO(CO) 3L]BF 4 complexes. The X-ray crystal structure of [C 5H 5Mo (CO) 3{P(C 6H 5) 3}]BF 4 is reported. The cation has the CpML 4 piano-stool geometry.

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