Abstract

In the title compound, C28H21Cl, the dihedral angle between the two fluorene ring systems is 71.97 (4)°. There is an intra­molecular C—H⋯Cl hydrogen bond. In the crystal structure, the centroid-to-centroid distance between stacked fluorene ring systems is ca 4.22 Å, which indicates that there are no π–π stacking inter­actions between them.

Highlights

  • In the title compound, C28H21Cl, the dihedral angle between the two fluorene ring systems is 71.97 (4)

  • The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry

  • F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^

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Summary

Data collection

Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.003 Å; Rfactor = 0.041; wR factor = 0.133; data-to-parameter ratio = 13.9. C28H21Cl, the dihedral angle between the two fluorene ring systems is 71.97 (4). There is an intramolecular C—H Cl hydrogen bond. The centroid-to-centroid distance between stacked fluorene ring systems is ca 4.22 Å, which indicates that there are no – stacking interactions between them

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