808 nm excited multi-color upconversion luminescence and optical temperature sensing through Yb3+-mediated energy transfer in Nd3+-sensitized system

Abstract

Herein, Na3Y(VO4)2:Nd3+,Yb3+,Ho3+/Er3+/Tm3+ are synthesized through the solid-state reaction method. By utilizing Yb3+-mediated energy transfer in Nd3+-sensitized various activators (Ho3+/Er3+/Tm3+) system, 808 nm excited multi-color upconversion luminescence is realized. Yb3+ plays an important role in energy transfer bridging, and the introduction of Yb3+ in Nd3+-sensitized system can significantly improve emission of activators by nearly two orders of magnitude. The main luminescence mechanism of Nd3+→Yb3+→Activators (Ho3+/Er3+/Tm3+) is proved via measuring the emission characteristics and luminescence decay curves. With efficient upconversion luminescence, the optical thermometry behaviors for Na3Y(VO4)2:Nd3+,Yb3+,Ho3+/Er3+/Tm3+ are investigated. The maximum relative and absolute sensitivities are 1.08 % K−1 and 7.82 × 10−3 K−1 for Na3Y(VO4)2:Nd3+,Yb3+,Er3+; 1.01 % K−1 and 4.22 × 10−3 K−1 for Na3Y(VO4)2:Nd3+,Yb3+,Tm3+; and 1.08 % K−1 and 22 × 10−3 K−1 for Na3Y(VO4)2:Nd3+,Yb3+,Ho3+, respectively. Based on the multi-color upconversion luminescence and high sensitivity thermometry performance, the Na3Y(VO4)2:Nd3+,Yb3+,Ho3+/Er3+/Tm3+ phosphors have potential applications in fields of solid-state display and safety sign of high-temperature.