Abstract

The stereoselective synthesis of functionalized, saturated N -heterocycles is a key challenge in modern synthesis and introduces avenues toward three-dimensional building blocks with vast potential in drug discovery. In this issue of Chem Catalysis , Blanc and co-workers report a Au(I)-catalyzed stereoselective cascade reaction that paves the way toward highly functionalized azepines. The stereoselective synthesis of functionalized, saturated N -heterocycles is a key challenge in modern synthesis and introduces avenues toward three-dimensional building blocks with vast potential in drug discovery. In this issue of Chem Catalysis , Blanc and co-workers report a Au(I)-catalyzed stereoselective cascade reaction that paves the way toward highly functionalized azepines.

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