Abstract
The title compound, [Co(C22H18N2O4)]·2CH2Cl2, was isolated from the reaction of N,N′(o-phenylene)bis(vanillalimine) (H2 L) with Co(SCN)2. The crystal structure contains a CoII ion surrounded by the L 2− ligand in a slightly distorted square-planar fashion. Intermolecular C—H⋯O hydrogen-bonding contacts between the dichloromethane solvent molecules and the methoxy or carboxylate O atoms are observed in the crystal structure. The planar complex molecules stack through inversion related π–π interactions between the six-membered rings of the vanillalimine half ligands. The distance between centroids is 3.498 (2) Å and the perpendicular distance is 3.345 Å. A partial stacking is observed with a centroid–centroid distance of 3.830 (2) Å, a perpendicular distance of 3.350 Å and a slippage of 1.856 Å.
Highlights
The title compound, [Co(C22H18N2O4)]Á2CH2Cl2, was isolated from the reaction of N,N0(o-phenylene)bis(vanillalimine) (H2L) with Co(SCN)2
The crystal structure contains a CoII ion surrounded by the L2À ligand in a slightly distorted square-planar fashion
Intermolecular C—HÁ Á ÁO hydrogenbonding contacts between the dichloromethane solvent molecules and the methoxy or carboxylate O atoms are observed in the crystal structure
Summary
Key indicators: single-crystal X-ray study; T = 150 K; mean (C–C) = 0.003 A; R factor = 0.046; wR factor = 0.089; data-to-parameter ratio = 17.9. The title compound, [Co(C22H18N2O4)]Á2CH2Cl2, was isolated from the reaction of N,N0(o-phenylene)bis(vanillalimine) (H2L) with Co(SCN). The crystal structure contains a CoII ion surrounded by the L2À ligand in a slightly distorted square-planar fashion. Intermolecular C—HÁ Á ÁO hydrogenbonding contacts between the dichloromethane solvent molecules and the methoxy or carboxylate O atoms are observed in the crystal structure. The planar complex molecules stack through inversion related – interactions between the sixmembered rings of the vanillalimine half ligands. The distance between centroids is 3.498 (2) Aand the perpendicular distance is 3.345 A. A partial stacking is observed with a centroid–centroid distance of 3.830 (2) A , a perpendicular distance of 3.350 Aand a slippage of 1.856 A
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have