Abstract
In the title compound, C25H26N2O4·CHCl3, the aromatic rings of the iminomethyl-6-methoxyphenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The molecular conformation is stabilized by intramolecular O—H⋯N hydrogen bonds. In the crystal, an intermolecular C—H⋯O hydrogen bond involving the chloroform solvent molecule is observed. The crystal packing is further stabilized by π–π stacking interactions [centroid–centroid distances = 3.739 (3)–3.776 (3) Å] between the benzene rings of centrosymmetrically related molecules.
Highlights
Bruker SMART APEX CCD areadetector diffractometerRint = 0.017 a Department of Chemistry, Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia, bDepartment of Chemical Sciences and Food
In the title compound, C25H26N2O4CHCl3, the aromatic rings of the iminomethyl-6-methoxyphenol fragments make dihedral angles of 58.33 (6) and 87.74 (6) with the central benzene ring
The molecular conformation is stabilized by intramolecular O—H N hydrogen bonds
Summary
Rint = 0.017 a Department of Chemistry, Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia, bDepartment of Chemical Sciences and Food. Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43650 Bangi, Selangor, Malaysia, and cDepartment of Chemical Sciences, Faculty of Science and Technology, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, Malaysia. C25H26N2O4CHCl3, the aromatic rings of the iminomethyl-6-methoxyphenol fragments make dihedral angles of 58.33 (6) and 87.74 (6) with the central benzene ring. The molecular conformation is stabilized by intramolecular O—H N hydrogen bonds. An intermolecular C—H O hydrogen bond involving the chloroform solvent molecule is observed. The crystal packing is further stabilized by – stacking interactions [centroid–. Centroid distances = 3.739 (3)–3.776 (3) Å] between the benzene rings of centrosymmetrically related molecules
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