Abstract
The benzoic acid molecule of the title adduct, C10H11N5·C7H6O2, is approximately planar, with a dihedral angle of 7.2 (3)° between the carboxylic acid group and the benzene ring. In the triazine molecule, the plane of the triazine ring makes a dihedral angle of 28.85 (9)° with that of the adjacent benzene ring. In the crystal, the two components are linked by N—H⋯O and O—H⋯N hydrogen bonds with an R 2 2(8) motif, thus generating a 1 + 1 unit of triazine and benzoic acid molecules. The acid–base units are further connected by N—H⋯N hydrogen bonds with R 2 2(8) motifs, forming a supramolecular ribbon along [101]. The crystal structure also features weak π–π [centroid–centroid distances = 3.7638 (12) and 3.6008 (12) Å] and C—H⋯π interactions.
Highlights
The benzoic acid molecule of the title adduct, C10H11N5C7H6O2, is approximately planar, with a dihedral angle of 7.2 (3) between the carboxylic acid group and the benzene ring
The two components are linked by N—H O and O—H N hydrogen bonds with an
For stability of the temperature controller used for the data collection, see: Cosier & Glazer (1986)
Summary
The benzoic acid molecule of the title adduct, C10H11N5C7H6O2, is approximately planar, with a dihedral angle of 7.2 (3) between the carboxylic acid group and the benzene ring. The plane of the triazine ring makes a dihedral angle of 28.85 (9) with that of the adjacent benzene ring. The two components are linked by N—H O and O—H N hydrogen bonds with an. R22(8) motif, generating a 1 + 1 unit of triazine and benzoic acid molecules. The acid–base units are further connected by. N—H N hydrogen bonds with R22(8) motifs, forming a supramolecular ribbon along [101]. The crystal structure features weak – [centroid–centroid distances = 3.7638 (12).
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