Abstract
In the title compound, [Cu(C16H11BrN2)(C18H33P)]BF4, the CuI atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromophenyl)-2,2′-bipyridine ligand and a P atom from the tricyclohexylphosphine ligand. In addition, a weak anion⋯CuI interaction with a nearest F⋯Cu separation of 2.696 (5) Å is found.
Highlights
CuI atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromophenyl)2,20 -bipyridine ligand and a P atom from the tricyclohexylphosphine ligand
We reported here a new three-coordinated copper(I)
The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry
Summary
A weak anion CuI interaction with a nearest F Cu separation of 2.696 (5) Å is found
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