Abstract
5-Thio- d-glucopyranosyl phosphate was prepared by reaction of the acetylated glycopyranosyl bromide with silver diphenyl phosphate followed by hydrogenolysis of the phenyl groups and deacetylation. 5-Thio- d-glucopyranose 6-phosphate was prepared from methyl 5-thio-2,3,4,6-tetra- O-(trimethylsilyl)-α- d-glucopyranoside by preferential removal of the trimethylsilyl group at O-6 by methanolysis, phosphorylation with diphenyl phosphorochloridate, and removal of the trimethylsilyl and phenyl groups. Both phosphates were obtained crystalline as their dicyclohexyl-ammonium salts.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
