Abstract
At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C5H5)(C15H20O4)]PF6, are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF6 − anion were found to be equally disordered over two sites.
Highlights
At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C5H5)(C15H20O4)]PF6, are almost parallel [dihedral angle between planes = 4.10 (14)]
Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom
The F atoms of the PF6À anion were found to be disordered over two sites
Summary
Key indicators: single-crystal X-ray study; T = 223 K; mean (C–C) = 0.003 A; disorder in solvent or counterion; R factor = 0.029; wR factor = 0.070; data-toparameter ratio = 12.4. At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C5H5)(C15H20O4)]PF6, are almost parallel [dihedral angle between planes = 4.10 (14)]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF6À anion were found to be disordered over two sites. Related literature For related literature, see: Abboud et al (1991); Crane (2003); Hanson (1982); Koray et al (1985); Marcen et al (2002); Piorko et al (1989, 1994)
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