57Fe Mössbauer and Co Kβ x-ray emission spectroscopic investigations of La-Co and La substituted strontium hexaferrite

Abstract

In the ferrite magnets, the magnetoplumbite-type strontium hexaferrite (SrFe12O19) is an important base material with a relatively high Curie temperature. The La-Co substitution in the Sr hexaferrites ((Sr,La)(Fe,Co)12O19) significantly improves magnetic coercivity. We have investigated the electronic states of Sr1−xLaxFe12−yCoyO19 by 57Fe Mössbauer and Co Kβ x-ray emission spectroscopies using the single-crystalline samples. The Co Kβ x-ray emission spectrum shows that all Co2+ ions are in the high-spin state. The hyperfine parameters extracted from the observed 57Fe Mössbauer spectra clearly show the Co and La substitution dependences at two Fe sites of the five crystallographically nonequivalent Fe sites, revealing that most Co2+ ions occupy the 4f1 and 2a Fe sites in Sr1−xLaxFe12−yCoyO19. These Co site occupations are consistent with the higher magnetic coercivity without a decrease in remanent magnetization in the La-Co substituted Sr hexaferrites.