Abstract
This chapter summarizes the recent progress on orange, red, and near-infrared thermally activated delayed fluorescent (TADF) emitters and the corresponding organic light-emitting diodes. General design principle for the TADF emitters are described, and the key problems in the long-wavelength emission region are further discussed. Focusing on the structure–performance relationship, the recent reported TADF emitters are reviewed with their molecular design, optoelectronic properties, and device performances, in the catalog of different type of acceptor units. This chapter not only offers a guideline for constructing highly efficient TADF emitters in the long-wavelength region, but also proposes a future prospect for the development and boarder applications of these emitters.
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